The current research aims to determine the impact of social capital in promoting successful pilot orientation through a survey of the views of employees in a group of small organizations. To achieve this the default chart has been prepared containing the search variables, as well as a number of main and subsidiary premises, and tested through a number of statistical methods, the questionnaire was used as a single tool to collect data and information from individual respondents and limited studies on the relationship Between these variables influence in Iraqi environment within the researcher informed, current research has included these variables in an attempt to study the relationship and influence between them. In General try to answer the question: what link relationships and impacts between social capital in promoting success factors leading direction in entering discussed? the researcher has been used as a tool to collect data and information to complete research and 40 have been distributed. The research has reached a set of conclusions: check a relation link between moral effects of social capital in promoting success orientation and leadership position. And a number of recommendations have been made compatible with those findings.

3-{(3–Methoxy–2–hydroxybenzylidene)amino}–2–thiohydantoin (3) was prepared via the reaction of 3– methoxy–2–hydroxybenzaldehyde (1) with thiosemicarbazide to give 1–{(3–methoxy–2–hydroxyl-benzylidene) amino}–thiourea (2), followed by cyclization of (2) with ethyl chloroacetate in the presence of fused sodium acetate. Treatment of compound (3) with aromatic aldehydes, 3–substituted phenacyl bromide and aryl diazonium salts afforded the corresponding 3–substituted–5–arylidene–2–thiohydantions (4a,b). Acetylation of compound (4) yielded the corresponding 1-Acetyl-3-{(3-methoxy-2-acetoxybenzylidene) amino}-5-arylidene -2-thiohydantions (5a,b). Alkylation of compound (3) afforded l–(aroyl) –methyl–3–substituted–2–thiohydantoins (6a,b). Also, Diazotization of aromatic amines with compound (3) gave 3–substituted–5–arylazo–2–thiohydantoins (7a,b), respectively. Their structures were characterized by IR,1H NMR, 13C NMR and elemental analyses. Some of the synthesized 2–thiohydantoin derivatives also exhibited antibacterial and antitumor activities.

In the present study, Human-Water Harmony Index (HWHI) was developed to evaluate the human-water relationship. HWHI model considers 22 basic indicators from three dimensions, water system (WS), human system (HS) and human water coordination system (CS). The developed model was then applied for the evaluation of human-water harmony status in five fast-developing cities, that are three in Pakistan - Karachi, Lahore, Faisalabad, and two in China - Nanjing and Zhang-YE. The result showed that the selected cities are confronting with human-water harmony challenges of varying degrees in different dimensions. Nanjing provides the best harmony status between human and water followed by Lahore, Zhang-Ye, Faisalabad and Karachi. The HWHI model provides the weaknesses and strengths of cities in specific sectors. Therefore, the development of HWHI will be helpful for the decision makers to devise strategies and policies to build the harmonious human-water harmony relationship. The approach presented in this study can be applied in other cities or regions round the World to evolve improved water management strategies for future sustainable development.